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• W1652707812 abstract "The diffuse v=0 to 4 levels of the 3pπu e′ 3Δu Rydberg state of O2 are identified and characterized using (3+1) resonance-enhanced multiphoton-ionization spectroscopy. An experimental potential-energy curve for the e′ state, together with the magnitude of its interaction with the A′ 3Δu valence state, are determined semiempirically by analyzing the predissociated spectra using the coupled-channel Schrödinger-equation method. The experimental Rydberg-valence coupling (930 cm−1) exceeds significantly the value calculated ab initio by Buenker and Peyerimhoff [Chem. Phys. Lett. 34, 225 (1975)] (&lt;320 cm−1), but is in good agreement with the single-configuration model prediction of Lewis et al. [J. Chem. Phys. 113, 2214 (2000)] (900 cm−1)." @default.
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• W1652707812 date "2001-05-15" @default.
• W1652707812 modified "2023-09-27" @default.
• W1652707812 title "Identification of the 3pπue′ 3Δu Rydberg state of O2 by (3+1) resonance-enhanced multiphoton-ionization spectroscopy" @default.
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• W1652707812 doi "https://doi.org/10.1063/1.1367333" @default.
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