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- W1652993 abstract "Simultaneous replacement of Sr by Ba and Y by Eu in the Pb-2213 system was found to yield single-phase ${mathrm{Pb}}_{2}$${mathrm{Ba}}_{2}$${mathrm{EuCu}}_{3}$${mathrm{O}}_{8+mathrm{ensuremath{delta}}}$ samples, suitable for $^{151}mathrm{Eu}$ Mossbauer measurements. The samples were synthesized by a solid-state reaction of metal oxides and carbonates under an inert atmosphere. An oxygen-rich sample corresponding to ensuremath{delta}=1.79 was obtained by annealing the as-synthesized material (ensuremath{delta}=0.16) in oxygen. The oxygen annealing increased the size of the lattice constants and led to an orthorhombic-to-tetragonal phase transition of the structure. The samples were also oriented in an 11.7-T magnetic field. The x-ray-diffraction spectra showed that the c axes tended to orient perpendicular to the applied field. The measured Mossbauer spectra exhibited an electric quadrupole interaction typical of the Eu site in high-${mathit{T}}_{mathit{c}}$ cuprates. The average orientation angles obtained from fittings of the Mossbauer spectra were in accordance with the results from the x-ray-diffraction measurements." @default.
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- W1652993 date "1994-12-01" @default.
- W1652993 modified "2023-09-26" @default.
- W1652993 title "Eu151Mössbauer spectroscopy and x-ray-diffraction studies on thePb2Ba2EuCu3O8+δsystem" @default.
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- W1652993 doi "https://doi.org/10.1103/physrevb.50.16040" @default.
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