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- W1653257032 abstract "The crystal structure of the newly discovered 117-K superconductor, (Cu,C)${mathrm{Ba}}_{2}$${mathrm{Ca}}_{3}$${mathrm{Cu}}_{4}$${mathrm{O}}_{11+mathrm{ensuremath{delta}}}$, has been refined from time-of-flight neutron-powder-diffraction data. The structure has ``average'' tetragonal symmetry and is similar to that of Tl(or Hg)${mathrm{Ba}}_{2}$${mathrm{Ca}}_{3}$${mathrm{Cu}}_{4}$${mathrm{O}}_{mathit{y}}$. C atoms in ${mathrm{CO}}_{3}$ groups substitute at the Cu site in the (Cu,C)${mathrm{O}}_{1+mathrm{ensuremath{delta}}}$ layer leading to a chemical composition of (${mathrm{Cu}}_{0.68}$${mathrm{C}}_{0.32}$)${mathrm{Ba}}_{2}$${mathrm{Ca}}_{3}$${mathrm{Cu}}_{4}$${mathrm{O}}_{11.06}$. This compound has two inequivalent kinds of ${mathrm{CuO}}_{2}$ layers with pyramidal and square coordination of Cu to oxygen. The inner ${mathrm{CuO}}_{2}$ layers with Cu in four coordination are less corrugated than the outer ones with Cu in five coordination, and exhibit a structure very similar to those of infinite-layer compounds." @default.
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- W1653257032 title "Crystal structure of (Cu,C)<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>Ba</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>Ca</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:…" @default.
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- W1653257032 doi "https://doi.org/10.1103/physrevb.50.16008" @default.
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