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• W1653647370 abstract "Nuclear magnetic resonance spectra of 209Bi(I=9/2) in the ferroelastic BiVO4 single crystal has been investigated by employing a wide-line Varian spectrometer. Only three lines due to a large quadrupole interaction were measured at a fixed frequency of 6 MHz in the principal planes at room temperature. From the experimental data the quadrupole coupling constant E2qQ/h=79.2+or-0.1 MHz and asymmetry parameter eta =0.70+or-0.01 are determined; however, these values turn out to be quite different from the previous report obtained with a ceramic sample at liquid-nitrogen temperature. The principal axes of the electric field gradient tensor are determined for the first time, the x, y and z axes being the crystallographic c+25 degrees , a+25 degrees , and b axes, respectively. Thes directions are discussed in terms of the Bi-O bonds in the Bi-O polyhedra." @default.
• W1653647370 created "2016-06-24" @default.
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• W1653647370 date "1992-02-10" @default.
• W1653647370 modified "2023-09-27" @default.
• W1653647370 title "Nuclear magnetic resonance of209Bi in a BiVO4single crystal" @default.
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• W1653647370 doi "https://doi.org/10.1088/0953-8984/4/6/026" @default.
• W1653647370 hasPublicationYear "1992" @default.
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