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- W1656064488 abstract "Two modifications of the <TEX>${alpha};and;{beta}$</TEX> forms of propyl mercaptan nickel(II) cluster, [<TEX>$Ni_6(SCH_2CH_2CH_3)_{12}$</TEX>], have been synthesized and their crystal structures have been determined by single-crystal X-ray diffraction. The alkyl groups are away from <TEX>$Ni_6$</TEX> ring in <TEX>$alpha$</TEX> form whereas they are near to the Ni atom in <TEX>$beta$</TEX> form. The distance of Ni-H in <TEX>$beta$</TEX> form [2.576(5) <TEX>$AA$</TEX>] is much shorter than that in <TEX>$alpha$</TEX> form [3.101(2) <TEX>$AA$</TEX>]. In the crystal lattice of <TEX>$beta$</TEX> form, the whole structure forms a flower shape." @default.
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- W1656064488 date "2009-04-20" @default.
- W1656064488 modified "2023-10-01" @default.
- W1656064488 title "Synthesis and Structure Analysis of α and β Forms of [12] Metallacrown-6 Nickel(II) Complex: [Ni6(SCH2CH2CH3)12]" @default.
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- W1656064488 doi "https://doi.org/10.5012/bkcs.2009.30.4.846" @default.
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