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- W1657250507 abstract "The series Y1-yCayBa2-yLayCu3O7-x, which is structurally related to YBa2Cu3O7-x, is of particular interest since the co-substitution of Ca (for Y) and La (for Ba) is electrically self-compensating. Seven samples with y<or=0.7 have been examined using powder neutron diffraction, and the detailed structural results used in an attempt to rationalize changes in superconducting behaviour. The limit of substitution corresponds to y=0.4 and, up to this limit, Tc decreases with increasing y. At higher values of y, only La enters the structure. The resulting charge imbalance is compensated by the introduction of additional oxygen and Tc remains approximately constant. The changes in Tc cannot simply be related to the Cu oxidation state, i.e. hole density in the Cu(2)O2 layers." @default.
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- W1657250507 date "1992-04-01" @default.
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- W1657250507 title "A neutron diffraction study of the system Y<sub>1-y</sub>Ca<sub>y</sub>Ba<sub>2-y</sub>La<sub>y</sub>Cu<sub>3</sub>O<sub>7-x</sub>" @default.
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- W1657250507 doi "https://doi.org/10.1088/0953-2048/5/4/002" @default.
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