Matches in SemOpenAlex for { <https://semopenalex.org/work/W1657368110> ?p ?o ?g. }
Showing items 1 to 92 of
92
with 100 items per page.
- W1657368110 endingPage "204" @default.
- W1657368110 startingPage "198" @default.
- W1657368110 abstract "Temperature programmed desorption (TPD) was used to investigate the adsorption and reaction of CH3SH and (CH3)2S2 on the nonpolar (101¯0) surface of ZnO. Methanethiol was found to dissociate on the (101¯0) surface to produce adsorbed methylthiolates. The primary reaction pathways for the methylthiolates were methyl group transfer between adjacent thiolates to produce (CH3)2S at 510 K, and transfer of methyl groups to surface lattice oxygen to produce adsorbed methoxides which were oxidized to CH2O at 525 K and adsorbed formate. Dimethyldisulfide was found to dissociate via cleavage of the S–S bond to form adsorbed methylthiolates. The reaction pathways for thiolates produced in this manner were similar to those produced from CH3SH except for an additional low-temperature pathway for the production of CH2O. Comparison of the results obtained in this study to our previous study of the reaction of CH3SH and (CH3)2S2 on ZnO(0 0 0 1) and published STM studies of ZnO(101¯0) and ZnO(0 0 0 1) indicates that step edges are the active sites for the reaction of thiols and disulfides on these surfaces." @default.
- W1657368110 created "2016-06-24" @default.
- W1657368110 creator A5003605373 @default.
- W1657368110 creator A5009685321 @default.
- W1657368110 date "2008-01-01" @default.
- W1657368110 modified "2023-09-24" @default.
- W1657368110 title "Site requirements for the reactions of CH3SH and (CH3)2S2 on ZnO()" @default.
- W1657368110 cites W1512292050 @default.
- W1657368110 cites W1963797858 @default.
- W1657368110 cites W1966083557 @default.
- W1657368110 cites W1992373357 @default.
- W1657368110 cites W1999340992 @default.
- W1657368110 cites W2002005771 @default.
- W1657368110 cites W2054350444 @default.
- W1657368110 cites W2055999197 @default.
- W1657368110 cites W2059323175 @default.
- W1657368110 cites W2074915437 @default.
- W1657368110 cites W2077190003 @default.
- W1657368110 cites W2132696982 @default.
- W1657368110 cites W2184874181 @default.
- W1657368110 cites W2335659416 @default.
- W1657368110 cites W4243198212 @default.
- W1657368110 cites W4254393267 @default.
- W1657368110 doi "https://doi.org/10.1016/j.susc.2007.10.010" @default.
- W1657368110 hasPublicationYear "2008" @default.
- W1657368110 type Work @default.
- W1657368110 sameAs 1657368110 @default.
- W1657368110 citedByCount "13" @default.
- W1657368110 countsByYear W16573681102012 @default.
- W1657368110 countsByYear W16573681102013 @default.
- W1657368110 countsByYear W16573681102014 @default.
- W1657368110 countsByYear W16573681102018 @default.
- W1657368110 crossrefType "journal-article" @default.
- W1657368110 hasAuthorship W1657368110A5003605373 @default.
- W1657368110 hasAuthorship W1657368110A5009685321 @default.
- W1657368110 hasConcept C147789679 @default.
- W1657368110 hasConcept C150394285 @default.
- W1657368110 hasConcept C159985019 @default.
- W1657368110 hasConcept C161790260 @default.
- W1657368110 hasConcept C162711632 @default.
- W1657368110 hasConcept C175156509 @default.
- W1657368110 hasConcept C178790620 @default.
- W1657368110 hasConcept C179104552 @default.
- W1657368110 hasConcept C185592680 @default.
- W1657368110 hasConcept C192562407 @default.
- W1657368110 hasConcept C2776353806 @default.
- W1657368110 hasConcept C2779870537 @default.
- W1657368110 hasConcept C2780178953 @default.
- W1657368110 hasConcept C3044715 @default.
- W1657368110 hasConcept C43369102 @default.
- W1657368110 hasConcept C518881349 @default.
- W1657368110 hasConcept C540031477 @default.
- W1657368110 hasConcept C75473681 @default.
- W1657368110 hasConceptScore W1657368110C147789679 @default.
- W1657368110 hasConceptScore W1657368110C150394285 @default.
- W1657368110 hasConceptScore W1657368110C159985019 @default.
- W1657368110 hasConceptScore W1657368110C161790260 @default.
- W1657368110 hasConceptScore W1657368110C162711632 @default.
- W1657368110 hasConceptScore W1657368110C175156509 @default.
- W1657368110 hasConceptScore W1657368110C178790620 @default.
- W1657368110 hasConceptScore W1657368110C179104552 @default.
- W1657368110 hasConceptScore W1657368110C185592680 @default.
- W1657368110 hasConceptScore W1657368110C192562407 @default.
- W1657368110 hasConceptScore W1657368110C2776353806 @default.
- W1657368110 hasConceptScore W1657368110C2779870537 @default.
- W1657368110 hasConceptScore W1657368110C2780178953 @default.
- W1657368110 hasConceptScore W1657368110C3044715 @default.
- W1657368110 hasConceptScore W1657368110C43369102 @default.
- W1657368110 hasConceptScore W1657368110C518881349 @default.
- W1657368110 hasConceptScore W1657368110C540031477 @default.
- W1657368110 hasConceptScore W1657368110C75473681 @default.
- W1657368110 hasIssue "1" @default.
- W1657368110 hasLocation W16573681101 @default.
- W1657368110 hasOpenAccess W1657368110 @default.
- W1657368110 hasPrimaryLocation W16573681101 @default.
- W1657368110 hasRelatedWork W1019971007 @default.
- W1657368110 hasRelatedWork W1980512307 @default.
- W1657368110 hasRelatedWork W2023200069 @default.
- W1657368110 hasRelatedWork W2046578753 @default.
- W1657368110 hasRelatedWork W2056369143 @default.
- W1657368110 hasRelatedWork W2078694791 @default.
- W1657368110 hasRelatedWork W2083116517 @default.
- W1657368110 hasRelatedWork W2367848283 @default.
- W1657368110 hasRelatedWork W3143522477 @default.
- W1657368110 hasRelatedWork W1984121029 @default.
- W1657368110 hasVolume "602" @default.
- W1657368110 isParatext "false" @default.
- W1657368110 isRetracted "false" @default.
- W1657368110 magId "1657368110" @default.
- W1657368110 workType "article" @default.