Matches in SemOpenAlex for { <https://semopenalex.org/work/W1657457712> ?p ?o ?g. }
Showing items 1 to 89 of
89
with 100 items per page.
- W1657457712 endingPage "19" @default.
- W1657457712 startingPage "17" @default.
- W1657457712 abstract "Dilute solutions in supercritical solvents exhibit interesting microstructures that are related to their dramatic macroscopic behavior. In typical attractive solutions, solutes are believed to be surrounded by clusters of solvent molecules, and solute molecules are believed to congregate in the vicinity of one another. Repulsive solutions, on the other hand, exhibit a local region of reduced solvent density around the solute with solute-solute congregation. Such microstructures influence solubility, partial molar volume, reaction kinetics, and many other properties. We have undertaken to observe these interesting microstructures directly by neutron scattering experiments on dilute noble gas systems including Ar. The three partial structure factors for such systems and the corresponding pair correlation functions can be determined by using the isotope substitution technique. The systems studied are uniquely suited for our objectives because of the large coherent neutron scattering length of the isotope {sup 36}Ar and because of the accurate potential energy functions that are available for use in molecular simulations and theoretical calculations to be compared with the scattering results. We will describe our experiment, the unique apparatus we have built for it, and the neutron scattering results from our initial allocations of beam time. We will also describe planned scattering experimentsmore » to follow those with noble gases, including study of long-chain molecules in supercritical solvents. Such studies will involve hydrocarbon mixtures with and without deuteration to provide contrast.« less" @default.
- W1657457712 created "2016-06-24" @default.
- W1657457712 creator A5005494816 @default.
- W1657457712 creator A5020035559 @default.
- W1657457712 creator A5055030412 @default.
- W1657457712 creator A5056662800 @default.
- W1657457712 creator A5079463407 @default.
- W1657457712 date "1994-10-01" @default.
- W1657457712 modified "2023-09-27" @default.
- W1657457712 title "Neutron scattering study of dilute supercritical solutions" @default.
- W1657457712 hasPublicationYear "1994" @default.
- W1657457712 type Work @default.
- W1657457712 sameAs 1657457712 @default.
- W1657457712 citedByCount "0" @default.
- W1657457712 crossrefType "journal-article" @default.
- W1657457712 hasAuthorship W1657457712A5005494816 @default.
- W1657457712 hasAuthorship W1657457712A5020035559 @default.
- W1657457712 hasAuthorship W1657457712A5055030412 @default.
- W1657457712 hasAuthorship W1657457712A5056662800 @default.
- W1657457712 hasAuthorship W1657457712A5079463407 @default.
- W1657457712 hasConcept C104015590 @default.
- W1657457712 hasConcept C115624301 @default.
- W1657457712 hasConcept C118419359 @default.
- W1657457712 hasConcept C120665830 @default.
- W1657457712 hasConcept C121332964 @default.
- W1657457712 hasConcept C121530826 @default.
- W1657457712 hasConcept C132841051 @default.
- W1657457712 hasConcept C147789679 @default.
- W1657457712 hasConcept C152568617 @default.
- W1657457712 hasConcept C155574463 @default.
- W1657457712 hasConcept C159467904 @default.
- W1657457712 hasConcept C178790620 @default.
- W1657457712 hasConcept C185544564 @default.
- W1657457712 hasConcept C185592680 @default.
- W1657457712 hasConcept C191486275 @default.
- W1657457712 hasConcept C192562407 @default.
- W1657457712 hasConcept C32909587 @default.
- W1657457712 hasConcept C73585123 @default.
- W1657457712 hasConcept C8010536 @default.
- W1657457712 hasConcept C97355855 @default.
- W1657457712 hasConceptScore W1657457712C104015590 @default.
- W1657457712 hasConceptScore W1657457712C115624301 @default.
- W1657457712 hasConceptScore W1657457712C118419359 @default.
- W1657457712 hasConceptScore W1657457712C120665830 @default.
- W1657457712 hasConceptScore W1657457712C121332964 @default.
- W1657457712 hasConceptScore W1657457712C121530826 @default.
- W1657457712 hasConceptScore W1657457712C132841051 @default.
- W1657457712 hasConceptScore W1657457712C147789679 @default.
- W1657457712 hasConceptScore W1657457712C152568617 @default.
- W1657457712 hasConceptScore W1657457712C155574463 @default.
- W1657457712 hasConceptScore W1657457712C159467904 @default.
- W1657457712 hasConceptScore W1657457712C178790620 @default.
- W1657457712 hasConceptScore W1657457712C185544564 @default.
- W1657457712 hasConceptScore W1657457712C185592680 @default.
- W1657457712 hasConceptScore W1657457712C191486275 @default.
- W1657457712 hasConceptScore W1657457712C192562407 @default.
- W1657457712 hasConceptScore W1657457712C32909587 @default.
- W1657457712 hasConceptScore W1657457712C73585123 @default.
- W1657457712 hasConceptScore W1657457712C8010536 @default.
- W1657457712 hasConceptScore W1657457712C97355855 @default.
- W1657457712 hasLocation W16574577121 @default.
- W1657457712 hasOpenAccess W1657457712 @default.
- W1657457712 hasPrimaryLocation W16574577121 @default.
- W1657457712 hasRelatedWork W1964235640 @default.
- W1657457712 hasRelatedWork W1984088018 @default.
- W1657457712 hasRelatedWork W1989234729 @default.
- W1657457712 hasRelatedWork W2005387222 @default.
- W1657457712 hasRelatedWork W2008020638 @default.
- W1657457712 hasRelatedWork W2019688849 @default.
- W1657457712 hasRelatedWork W2028515247 @default.
- W1657457712 hasRelatedWork W2032163491 @default.
- W1657457712 hasRelatedWork W2059883340 @default.
- W1657457712 hasRelatedWork W2147216739 @default.
- W1657457712 hasRelatedWork W2165703451 @default.
- W1657457712 hasRelatedWork W2320302128 @default.
- W1657457712 hasRelatedWork W2323731397 @default.
- W1657457712 hasRelatedWork W2329726931 @default.
- W1657457712 hasRelatedWork W256231049 @default.
- W1657457712 hasRelatedWork W2976601353 @default.
- W1657457712 hasRelatedWork W3099688756 @default.
- W1657457712 hasRelatedWork W3102265991 @default.
- W1657457712 hasRelatedWork W3103793254 @default.
- W1657457712 hasRelatedWork W2460322182 @default.
- W1657457712 isParatext "false" @default.
- W1657457712 isRetracted "false" @default.
- W1657457712 magId "1657457712" @default.
- W1657457712 workType "article" @default.