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- W1657503524 abstract "The (001) surface of magnetite has been studied using Auger electron spectroscopy (AES), low energy electron diffraction (LEED) and scanning tunneling microscopy (STM). A clean, octahedrally terminated surface was obtained by a combination of in‐situ annealing in an O2 atmosphere, Ar+ ion etching and subsequent annealing in UHV. LEED exhibits a (√ × √)R45° mesh. STM was carried out with probes made from antiferromagnetic MnNi. Atomically resolved images of the octahedrally terminated surface show rows, running along the [110] direction, separated by 6 A. Along these rows two different atomic scale features are imaged, with a periodicity of 6 A, as opposed to the 3 A periodicity of the Fe ions expected for bulk terminated magnetite (001). A model explaining the observed symmetry in terms of charge ordering of the Fe2+ and Fe3+ cations, on the surface octahedral sites, is proposed." @default.
- W1657503524 created "2016-06-24" @default.
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- W1657503524 date "2003-01-01" @default.
- W1657503524 modified "2023-09-27" @default.
- W1657503524 title "Charge Ordering on the (√2 × √2)R45° Reconstructed Fe3O4 (001) Surface" @default.
- W1657503524 doi "https://doi.org/10.1063/1.1639796" @default.
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