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- W1657793986 abstract "This chapter focuses on carbon monoxide as a reagent in M–NHC catalysed reactions. The most important and popular of these reactions is hydroformylation. Unfortunately, uncertainty exists as to the identity of the active catalyst and whether the NHC is bound to the catalyst in a number of the reported reactions. Mixed bidentate NHC complexes and cobalt-based complexes provide for better stability of the catalyst. Catalysts used for hydroaminomethylation and carbonylation reactions show promise to rival traditional phosphine-based catalysts. Reports of decarbonylation are scarce, but the potential strength of the M–NHC bond is conducive to the harsh conditions required. This report will highlight, where appropriate, the potential benefits of exchanging traditional phosphorous ligands with N-heterocyclic carbenes as well as cases where the role of the NHC might need re-evaluation. A review by the author on this topic has recently appeared [1]." @default.
- W1657793986 created "2016-06-24" @default.
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- W1657793986 date "2010-01-01" @default.
- W1657793986 modified "2023-09-26" @default.
- W1657793986 title "N-Heterocyclic Carbene Complexes in Reactions Involving Carbon Monoxide" @default.
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- W1657793986 doi "https://doi.org/10.1007/978-90-481-2866-2_9" @default.
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