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- W1659202276 abstract "In column chromatography, especially when trace amounts of analytes are to be determined, it is instructive to describe quantitatively the effects of the individual experimental parameters on the sensitivity of analysis1-4. The sensitivity of chromatographic analysis depends, among other factors, on the manner in which the sample is introduced into the column. However, a quantitative evaluation of the actual significance of the column inlet concentration profile in this respect has been lacking. The purpose of this paper is to present a simple general model that shows the extent to which the sensitivity of analysis is affected by the shape of the column inlet concentration profile of the analyte. The sensitivity of analysis, i.e., the performance of the chromatographic column detector system, is expressed here through the sensitivity of analyte mass determination. The sensitivity of analyte mass determination is related to the zone-maximum analyte concentration per unit mass of analyte in the mobile phase at the column 0utleW." @default.
- W1659202276 created "2016-06-24" @default.
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- W1659202276 date "1987-01-01" @default.
- W1659202276 modified "2023-10-18" @default.
- W1659202276 title "Effect of column inlet concentration profile on the sensitivity of analysis" @default.
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- W1659202276 doi "https://doi.org/10.1016/s0021-9673(01)86813-8" @default.
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