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- W1660231983 abstract "Transient BaF2-based oxyfluoride phases are thought to play a critical role in the formation of the c-textured Ba2YCu3O7−x layers of coated conductors. In situ high-temperature x-ray diffraction from the precursor films containing pure BaF2 as well as pseudobinary BaF2–Y, BaF2–Cu, and Y–Cu mixtures and heat treated in water vapor under reduced conditions revealed that the transient BaF2-based superstructures, similar to those observed during formation of Ba2Cu3O7−x, develop even from the pure BaF2 precursor. These superstructures results from the dissolution of oxygen in BaF2 leading to formation of the oxyfluoride phase, Ba(F2−2x◻x)Ox, with an ordered arrangement of O, F, and F vacancies." @default.
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- W1660231983 date "2006-03-06" @default.
- W1660231983 modified "2023-10-16" @default.
- W1660231983 title "Nature of the transient BaF2-related phases in the “BaF2” processing of Ba2YCu3O7−x superconductors" @default.
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- W1660231983 doi "https://doi.org/10.1063/1.2184757" @default.
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