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• W1660403750 startingPage "1607" @default.
• W1660403750 abstract "The luminescences of isomeric nitroanilines and their N-methylated derivatives, as observed in glassy media at 77°K, are reported. The o- and m-derivatives fluoresce only. The p-derivatives may fluoresce only, phosphoresce only, or show both a fluorescence and a phosphorescence whose relative intensities are dependent on the polarity of the medium and the exciting wavelength. These p-derivatives which possess the largest ground-state dipole moments exhibit the largest phosphorescence yields; they also exhibit a dependence of φp/φf on excitation energies which lie within the wavelength compass of the lowest-energy absorption band, a ``red-edge'' effect, and different fluorescence and phosphorescence excitation spectra. Some suggestions as to the interpretation of these effects are made." @default.
• W1660403750 created "2016-06-24" @default.
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• W1660403750 creator A5043064293 @default.
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• W1660403750 date "1973-02-15" @default.
• W1660403750 modified "2023-10-16" @default.
• W1660403750 title "Electronic spectroscopy of highly-polar aromatics.* II. Luminescence of nitroanilines" @default.
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• W1660403750 doi "https://doi.org/10.1063/1.1679401" @default.
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