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- W166065269 abstract "The electrochemical reduction of americium in acetonitrile medium was investigated. On the basis of the data obtained and a comparison of them with the results of a study of the mechanism of the reduction of rare-earth elements, it was suggested that americium is reduced through the divalent state. Unstable Am/sup 2 +/ cations are oxidized by the water contained in the solvent, with the formation of the hydrolyzed form of trivalent americium. The reduction of the latter ends in the liberation of a precipitate of a basic salt with composition Am(OH)/sub 2/./sub 6/(ClO/sub 4/)/sub 0/./sub 4/. The formal redox potential of the couple Am(III)/Am(II) in acetonitrile, equal to -1.55 V, was estimated." @default.
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- W166065269 date "1975-01-01" @default.
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- W166065269 title "Electrochemical reduction of americium in acetonitrile medium" @default.
- W166065269 hasPublicationYear "1975" @default.
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