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W1661062021 abstract "Dehydroabietic acid (DHA, 1 ), a natural occurring diterpene resin acid, is an abundant resin acid in conifers, representing a natural wood protectant. The aim of this study was to use microbial cell cultures as tools for modification of 1 in order to obtain value-added functional derivatives. A scaled-up biotransformation of 1 by filamentous fungus Cunninghamella elegans , Rhizopus stolonifer , Gibberella fujikuroi , and Cephalosporium aphidicola were conducted for the first time. Three hydroxylated metabolites; 1b-hydroxydehydroabietic acid ( 2 ); 15-hydroxy dehydroabietic acid ( 3 ); and 16-hydroxy dehydroabietic acid ( 4 ). The structure of the hydroxylated metabolites were elucidated by 1-D ( 1 H, 13 C) and 2-D NMR (COSY, HMBC, HMQC, NOESY) techniques and MS analyses. Dehydroabietic acid ( 1 ) and their transformed products 2 - 4 exhibited a promising α-Glucosidase inhibitory activity. Compound 1 showed 38 times more active than the standard α-Glucosidase inhibitor, deoxynojirimycin. Compound 1 and its transformed metabolites 2 - 4 also showed significant antibacterial activities. Keywords: Microbial transformation, Dehydroabietic acid, Antibacterial activities, α-Glucosidase." @default.
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W1661062021 date "2014-07-29" @default.
W1661062021 modified "2023-09-22" @default.
W1661062021 title "BIOTRANSFORMATION OF DEHYDROABIETIC ACID WITH MICROBIAL CELL CULTURES AND α-GLUCOSIDASE INHIBITORY ACTIVITY OF RESULTING METABOLITES" @default.
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