Matches in SemOpenAlex for { <https://semopenalex.org/work/W1661555257> ?p ?o ?g. }
Showing items 1 to 73 of
73
with 100 items per page.
- W1661555257 abstract "This thesis reports the studies of a series of novel π-conjugated organic hybrid materials undertaken throughout my PhD research. In the synthetic work, the Cu(I)-catalyzed azide-alkyne [3+2] cycloaddition, one of the most popular reactions, has been successfully utilized to covalently attach a series of azido-pendant Frechet-type dendrimers to various alkynylated π-conjugated building-blocks, ranging from [60]fullerene, porphyrin, tetrathiafulvalene (TTF) analogues, and linear/star-shaped conjugated phenylene ethynylene oligomers (OPEs), in a modular fashion. The resulting hybrid macromolecules show rich photophysical, electrochemical, and surface morphological properties, which are potentially useful for the application in molecular optoelectronic devices. The most remarkable finding resulting from the click comes from a class of dendro[60]fullerenes, which show interesting surface self-assembly behavior to form controllable nanostructures. The correlation between aggregation behavior and molecular parameters has been examined, and the results indicate that the surface self-assembling properties of these dendro[60]fullerenes are dependent on dendron generation, the nature of the end-groups, and acidity. Moreover, a class of electron-rich polyynes has been synthesized, in which redox active 1,3-dithiole and ferrocenyl end groups are incorporated into the polyynes. Potential of these polyyne-TTF hybrids in making electrochemically active conducting polymer materials has been explored based on voltammetric and spectroscopic characterization. Finally, the thesis work has developed the synthesis of a series of poly(ethylene glycol) (PEG) functionalized conjugated arylene polymers as well as a group of imidazolium-based ionic liquids. These materials are specially designed for functionalization of single-walled carbon nanotubes (SWNTs) through non-covalent and covalent approaches." @default.
- W1661555257 created "2016-06-24" @default.
- W1661555257 creator A5008869858 @default.
- W1661555257 date "2009-01-01" @default.
- W1661555257 modified "2023-09-26" @default.
- W1661555257 title "Synthesis and characterization of molecular materials derived from dendrimers, [60]fullerene, and linear π-conjugated oligomers" @default.
- W1661555257 hasPublicationYear "2009" @default.
- W1661555257 type Work @default.
- W1661555257 sameAs 1661555257 @default.
- W1661555257 citedByCount "0" @default.
- W1661555257 crossrefType "dissertation" @default.
- W1661555257 hasAuthorship W1661555257A5008869858 @default.
- W1661555257 hasConcept C112613896 @default.
- W1661555257 hasConcept C115537861 @default.
- W1661555257 hasConcept C147789679 @default.
- W1661555257 hasConcept C161790260 @default.
- W1661555257 hasConcept C162862793 @default.
- W1661555257 hasConcept C178790620 @default.
- W1661555257 hasConcept C185592680 @default.
- W1661555257 hasConcept C188027245 @default.
- W1661555257 hasConcept C192562407 @default.
- W1661555257 hasConcept C21951064 @default.
- W1661555257 hasConcept C2778421084 @default.
- W1661555257 hasConcept C2779664164 @default.
- W1661555257 hasConcept C2780997848 @default.
- W1661555257 hasConcept C32909587 @default.
- W1661555257 hasConcept C521977710 @default.
- W1661555257 hasConcept C55637122 @default.
- W1661555257 hasConcept C69610077 @default.
- W1661555257 hasConceptScore W1661555257C112613896 @default.
- W1661555257 hasConceptScore W1661555257C115537861 @default.
- W1661555257 hasConceptScore W1661555257C147789679 @default.
- W1661555257 hasConceptScore W1661555257C161790260 @default.
- W1661555257 hasConceptScore W1661555257C162862793 @default.
- W1661555257 hasConceptScore W1661555257C178790620 @default.
- W1661555257 hasConceptScore W1661555257C185592680 @default.
- W1661555257 hasConceptScore W1661555257C188027245 @default.
- W1661555257 hasConceptScore W1661555257C192562407 @default.
- W1661555257 hasConceptScore W1661555257C21951064 @default.
- W1661555257 hasConceptScore W1661555257C2778421084 @default.
- W1661555257 hasConceptScore W1661555257C2779664164 @default.
- W1661555257 hasConceptScore W1661555257C2780997848 @default.
- W1661555257 hasConceptScore W1661555257C32909587 @default.
- W1661555257 hasConceptScore W1661555257C521977710 @default.
- W1661555257 hasConceptScore W1661555257C55637122 @default.
- W1661555257 hasConceptScore W1661555257C69610077 @default.
- W1661555257 hasLocation W16615552571 @default.
- W1661555257 hasOpenAccess W1661555257 @default.
- W1661555257 hasPrimaryLocation W16615552571 @default.
- W1661555257 hasRelatedWork W1571937310 @default.
- W1661555257 hasRelatedWork W1982485120 @default.
- W1661555257 hasRelatedWork W2006662954 @default.
- W1661555257 hasRelatedWork W2041972427 @default.
- W1661555257 hasRelatedWork W2085615005 @default.
- W1661555257 hasRelatedWork W2113067461 @default.
- W1661555257 hasRelatedWork W2117941278 @default.
- W1661555257 hasRelatedWork W2124032549 @default.
- W1661555257 hasRelatedWork W2181481205 @default.
- W1661555257 hasRelatedWork W2321359631 @default.
- W1661555257 hasRelatedWork W2331921892 @default.
- W1661555257 hasRelatedWork W2578884342 @default.
- W1661555257 hasRelatedWork W2790124405 @default.
- W1661555257 hasRelatedWork W2798004632 @default.
- W1661555257 hasRelatedWork W2949413026 @default.
- W1661555257 hasRelatedWork W2950424384 @default.
- W1661555257 hasRelatedWork W2950907955 @default.
- W1661555257 hasRelatedWork W3180090552 @default.
- W1661555257 hasRelatedWork W65140956 @default.
- W1661555257 hasRelatedWork W88919152 @default.
- W1661555257 isParatext "false" @default.
- W1661555257 isRetracted "false" @default.
- W1661555257 magId "1661555257" @default.
- W1661555257 workType "dissertation" @default.