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- W1661576376 abstract "The C-H stretch vibrational modes of ${mathrm{CH}}_{3}$O chemisorbed on a Cu(100) surface have been studied using infrared spectroscopy. Three absorption peaks were found indicating that the symmetry of the ${mathrm{CH}}_{3}$ group is broken. Comparison with the infrared spectra of free methanol shows that the ${mathrm{CH}}_{3}$O group is rather little perturbed by the chemisorption and that the molecules definitely are tilted on the surface. Thermal desorption spectra indicate that the dehydrogenation of ${mathrm{CH}}_{3}$O to ${mathrm{H}}_{2}$CO goes via the adsorption of a hydrogen atom on the copper surface during a low frequency bending mode." @default.
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- W1661576376 date "1985-02-15" @default.
- W1661576376 modified "2023-09-23" @default.
- W1661576376 title "Symmetry and orientation of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>CH</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>O on Cu(100)" @default.
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- W1661576376 doi "https://doi.org/10.1103/physrevb.31.2545" @default.
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