Matches in SemOpenAlex for { <https://semopenalex.org/work/W1663703804> ?p ?o ?g. }
Showing items 1 to 77 of
77
with 100 items per page.
- W1663703804 endingPage "173" @default.
- W1663703804 startingPage "169" @default.
- W1663703804 abstract "A general relation has been given relating the slope of the isotherms along the liquid-vapor coexistence curve to the shape of the latter, and has been applied to the case where the coexistence curve is rounded on the top and to the case where it has a flat horizontal portion. If the coexistence curve has the form T—Tc = — a|ρc—ρ|n (where T = temperature, ρ=density, subscript c indicates a value at the critical point, and a and n are constants) it can be shown that the critical isotherm is given by P−Pc=a(∂2P/∂T∂ρ)c(ρ−ρc)|ρ−ρc|n,provided (∂2P/∂T∂ρ)c is finite. This equation should hold over the region where ∂2P/∂T∂ρ is approximately constant. If there is a flat, horizontal portion at the top of the isotherm a similar equation will be approximately true under the same conditions beyond the flat portion. The actual shape of experimental isotherms in the critical region is considered. ∂2P/∂T∂ρ is approximately constant only over a limited range of densities, and beyond this range the slopes of the isotherms become greater than indicated by the equation; however, general orders of magnitude are as expected. It is not possible to decide definitely from the data considered whether the critical isotherm has a horizontal region over a finite range of densities. Finally, a discussion is given of the discontinuities of thermodynamic quantities, particularly Cv, as one passes from the one-phase to the two-phase region. It is shown that Cv must be much larger in the two-phase than in the one-phase region." @default.
- W1663703804 created "2016-06-24" @default.
- W1663703804 creator A5088994302 @default.
- W1663703804 date "1955-01-01" @default.
- W1663703804 modified "2023-09-27" @default.
- W1663703804 title "Relation between Isotherms and Coexistence Curve in the Critical Region" @default.
- W1663703804 cites W1965561065 @default.
- W1663703804 cites W1973182758 @default.
- W1663703804 cites W1980510833 @default.
- W1663703804 cites W2005947537 @default.
- W1663703804 cites W2035701685 @default.
- W1663703804 cites W2042732062 @default.
- W1663703804 cites W2084661745 @default.
- W1663703804 doi "https://doi.org/10.1063/1.1740520" @default.
- W1663703804 hasPublicationYear "1955" @default.
- W1663703804 type Work @default.
- W1663703804 sameAs 1663703804 @default.
- W1663703804 citedByCount "10" @default.
- W1663703804 crossrefType "journal-article" @default.
- W1663703804 hasAuthorship W1663703804A5088994302 @default.
- W1663703804 hasConcept C119094556 @default.
- W1663703804 hasConcept C121332964 @default.
- W1663703804 hasConcept C134306372 @default.
- W1663703804 hasConcept C15627037 @default.
- W1663703804 hasConcept C159985019 @default.
- W1663703804 hasConcept C185592680 @default.
- W1663703804 hasConcept C192562407 @default.
- W1663703804 hasConcept C196298200 @default.
- W1663703804 hasConcept C199360897 @default.
- W1663703804 hasConcept C204323151 @default.
- W1663703804 hasConcept C2524010 @default.
- W1663703804 hasConcept C2777027219 @default.
- W1663703804 hasConcept C33923547 @default.
- W1663703804 hasConcept C41008148 @default.
- W1663703804 hasConcept C44280652 @default.
- W1663703804 hasConcept C62520636 @default.
- W1663703804 hasConcept C85906118 @default.
- W1663703804 hasConcept C97355855 @default.
- W1663703804 hasConceptScore W1663703804C119094556 @default.
- W1663703804 hasConceptScore W1663703804C121332964 @default.
- W1663703804 hasConceptScore W1663703804C134306372 @default.
- W1663703804 hasConceptScore W1663703804C15627037 @default.
- W1663703804 hasConceptScore W1663703804C159985019 @default.
- W1663703804 hasConceptScore W1663703804C185592680 @default.
- W1663703804 hasConceptScore W1663703804C192562407 @default.
- W1663703804 hasConceptScore W1663703804C196298200 @default.
- W1663703804 hasConceptScore W1663703804C199360897 @default.
- W1663703804 hasConceptScore W1663703804C204323151 @default.
- W1663703804 hasConceptScore W1663703804C2524010 @default.
- W1663703804 hasConceptScore W1663703804C2777027219 @default.
- W1663703804 hasConceptScore W1663703804C33923547 @default.
- W1663703804 hasConceptScore W1663703804C41008148 @default.
- W1663703804 hasConceptScore W1663703804C44280652 @default.
- W1663703804 hasConceptScore W1663703804C62520636 @default.
- W1663703804 hasConceptScore W1663703804C85906118 @default.
- W1663703804 hasConceptScore W1663703804C97355855 @default.
- W1663703804 hasIssue "1" @default.
- W1663703804 hasLocation W16637038041 @default.
- W1663703804 hasOpenAccess W1663703804 @default.
- W1663703804 hasPrimaryLocation W16637038041 @default.
- W1663703804 hasRelatedWork W1967878322 @default.
- W1663703804 hasRelatedWork W1973725045 @default.
- W1663703804 hasRelatedWork W2016665629 @default.
- W1663703804 hasRelatedWork W2020582182 @default.
- W1663703804 hasRelatedWork W2032795482 @default.
- W1663703804 hasRelatedWork W2094884684 @default.
- W1663703804 hasRelatedWork W2106975948 @default.
- W1663703804 hasRelatedWork W3100661230 @default.
- W1663703804 hasRelatedWork W4251309917 @default.
- W1663703804 hasRelatedWork W1991903219 @default.
- W1663703804 hasVolume "23" @default.
- W1663703804 isParatext "false" @default.
- W1663703804 isRetracted "false" @default.
- W1663703804 magId "1663703804" @default.
- W1663703804 workType "article" @default.