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- W1663704773 abstract "The present work investigates the effect of La substitution at the Ba site on the structural and normal state properties of the PrBa2-xLaxCu3O7-δ compound, with various x values (0.00⩽x⩽1.00). X-ray diffraction results indicate that the c lattice parameter decreases with increasing x for all samples. The samples with x = 0.00 and 0.25 are clearly quasi-tetragonal single phase, while the samples with x = 0.50, 0.75 and 1.00 are clearly orthorhombic single phase with a few small unreacted lines observed in the spectrum of the x = 1.0 sample. The effective Cu valence decreases linearly with increasing La content along with a small increase in the oxygen content. The EDX analysis reveals that the total amount of La and Ba remains constant with increasing La content. It is also found that the substitution of La at the Ba site leads to an unusual drop in the normal state resistivity as compared to the Pr:123 compound. We suggest that both the hole filling and oxygen disorder effects might be key parameters controlling superconductivity as well as the normal state properties of the Pr:123 compound. Our results are supported by a host of other considerations and experimental observations." @default.
- W1663704773 created "2016-06-24" @default.
- W1663704773 creator A5039279514 @default.
- W1663704773 date "2001-05-04" @default.
- W1663704773 modified "2023-10-16" @default.
- W1663704773 title "Structural and normal state properties of the PrBa2-xLaxCu3O7-δcompound with (0.00⩽x⩽1.00)" @default.
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- W1663704773 doi "https://doi.org/10.1088/0953-8984/13/20/306" @default.
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