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- W1665344265 abstract "The adsorption of nitrous oxide, N2O, on a Rh(110) surface has been characterized by using density-functional theory. N2O was found to bind to the surface in two alternative forms. The first, less stable form is tilted with the terminal N atom attached to the surface, while the second, more stable form lies horizontally on the surface. Adsorption on the on-top site is more stable than that on the bridge site. The tilted form remains linear on adsorption, while the horizontal form is bent, with the terminal-nitrogen and oxygen atoms pointing towards the surface. At lower adsorbate coverage, Θ≲1/4 ML (ML—monolayer), the adsorption of a few horizontal N2O configurations is dissociative, i.e., N2O→N2(a)+O(a). The N2O-surface interaction is discussed in terms of the electronic structure analysis." @default.
- W1665344265 created "2016-06-24" @default.
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- W1665344265 date "2005-01-03" @default.
- W1665344265 modified "2023-09-29" @default.
- W1665344265 title "A density-functional theory study of the interaction of N2O with Rh(110)" @default.
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- W1665344265 doi "https://doi.org/10.1063/1.1829652" @default.
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