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- W1665883782 abstract "Abstract The configuration and conformation of a series of α-alkyl-β-monoalkyl- and α-alkyl-β-dialkylamino-α,β-unsaturated carbonyl compounds have been established by means of IR and 1 H NMR spectroscopy. A comparison of the maximum absorption of the S 0 → S 1 (π,π * ) transition of derivatives of related structures yielded the spectral constants characteristic of structural features. These are: Δλ g−Z g−E = 12−17 nm (Δν s−Z s−E = −1320 to −1820 cm −1 , Δλ H-bond intra = 17−22 nm (Δν H-bond intra = −2060 to −2690 cm −1 ), Δλ Z−s−Z α-alk = 13 nm (Δν Z−s−Z α-alk = −1340 cm −1 ) and Δλ N-alk 2 NH-alk = 11 nm (Δν N-alk 2 NH-alk = −1330 cm −1 ). The applicability of the system of spectral increments described for simple enamino aldehydes, ketones and amides has been entirely corroborated." @default.
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- W1665883782 date "1983-10-01" @default.
- W1665883782 modified "2023-09-26" @default.
- W1665883782 title "Structural increments in UV spectra of conjugated carbonyl compounds" @default.
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- W1665883782 doi "https://doi.org/10.1016/0022-2860(83)80001-5" @default.
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