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• W1666229178 abstract "The charge transfer reaction DBr+(2∏I,v+,J+)+HBr→HBr+(2∏I′,v′+,J′+)+DBr is studied in a state-to-state manner under thermal conditions in a slowly flowing gas mixture of HBr and DBr. The DBr+ reagent is prepared in a selected vibronic level by using (2+1) resonance-enhanced multiphoton ionization. The HBr+ product is detected in a quantum-state-specific manner using laser-induced fluorescence. From the measurements of the molecular density and the populations of both HBr+ product and DBr+ reagent, the absolute thermal rate constants k(i,v+→i′,v′+) are determined for this charge-transfer process. The rate constants for near-resonant charge transfer in which Δv+=0 and Δi=0 are much large than charge-transfer channels in which either Δi≠0; the smallest rate constants are for those channels in which both Δi≠0 and Δv+≠0. The rotational distribution of the HBr+(i′,v′+) products fits a temperature well in each case. For near-resonant charge transfer, the rotational temperature is slightly warmer than thermal, whereas for nonresonant charge transfer, the rotational temperature is much hotter than thermal. A model in which the excess energy of a charge-transfer process is statistically partitioned among all the degrees of freedom of the complex is able to predict closely the observed rotational temperature." @default.
• W1666229178 created "2016-06-24" @default.
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• W1666229178 date "1992-03-15" @default.
• W1666229178 modified "2023-10-16" @default.
• W1666229178 title "Determination of absolute thermal rate constants for the charge-transfer reaction DBr+(2∏I,v+)+HBr→HBr+(2∏I′,v′+)+DBr" @default.
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• W1666229178 doi "https://doi.org/10.1063/1.462916" @default.
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