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- W1669240610 abstract "Silica surfaces, created and maintained under UHV, possess dangling bonds; the E′s centres are those dangling bonds which are paramagnetic. As shown by the g(g‖ = 2.0018, g⊥ = 2.0003) and the hfs[a(29Si) = 435 × 10−4cm−1] constants, these centres are formed by an unpaired electron trapped on a surface silicon atom and thus are Si dangling bonds. The adsorption of carbon dioxide on silica takes place on these dangling bonds, with formation of Si+CO2− complexes by partial charge transfer (a13C) = 203 × 10−4 cm−4, a(su29Si) = 115 × 10−4 cm−1], from E′s to the CO2 molecule. The CO2 thermal desorption is possible and complete below 250 °C, and takes place simultaneously with an inverse charge transfer." @default.
- W1669240610 created "2016-06-24" @default.
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- W1669240610 date "1972-09-01" @default.
- W1669240610 modified "2023-10-17" @default.
- W1669240610 title "Surface states of pristine silica surfaces" @default.
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- W1669240610 doi "https://doi.org/10.1016/0039-6028(72)90192-6" @default.
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