Matches in SemOpenAlex for { <https://semopenalex.org/work/W1670111524> ?p ?o ?g. }
- W1670111524 abstract "Publisher Summary Cationic polymerization is the conversion of low molecular weight monomeric molecules into high molecular weight polymeric ones, through a mechanism involving stepwise growth of a carbonium (R 3 C + ), carboxoniup, oxonium (R 3 0 + ), sulphonium (R 3 S + ), or immonium (R 2 N + =CŔ 2 ) ion. This chapter reviews the kinetic and mechanistic aspects of cationic polymerizations and analyzes the limited reliable kinetic data. The chapter outlines the complex nature of cationic systems and discusses that in any kinetic experiment of quantitative value, firstly data on the rate of propagation alone as opposed to an overall rate of polymerization must be ascertained. Secondly, the proportion of free ions and paired species ( α or K d ) must be known. Finally, in order to determine the two unknowns, that is, the rate coefficient for propagation by free ions, and the rate coefficient for propagation by ion pairs, either their approximate relative values must be known, or the proportion of each species must be altered by some arbitrary procedure (for instance, changing the total concentration, or use of “common ion” effect)." @default.
- W1670111524 created "2016-06-24" @default.
- W1670111524 creator A5003670054 @default.
- W1670111524 creator A5087151990 @default.
- W1670111524 date "1976-01-01" @default.
- W1670111524 modified "2023-09-24" @default.
- W1670111524 title "Chapter 2 Kinetics of Homogeneous Cationic Polymerization" @default.
- W1670111524 cites W1484848346 @default.
- W1670111524 cites W1487661158 @default.
- W1670111524 cites W1487829271 @default.
- W1670111524 cites W1490737583 @default.
- W1670111524 cites W1497844468 @default.
- W1670111524 cites W1503708622 @default.
- W1670111524 cites W1522811495 @default.
- W1670111524 cites W1551474461 @default.
- W1670111524 cites W1556181125 @default.
- W1670111524 cites W1556901886 @default.
- W1670111524 cites W1578752610 @default.
- W1670111524 cites W1591989967 @default.
- W1670111524 cites W1954066274 @default.
- W1670111524 cites W1967867685 @default.
- W1670111524 cites W1968676191 @default.
- W1670111524 cites W1972683738 @default.
- W1670111524 cites W1974245705 @default.
- W1670111524 cites W1974540481 @default.
- W1670111524 cites W1978977191 @default.
- W1670111524 cites W1990051248 @default.
- W1670111524 cites W1995131994 @default.
- W1670111524 cites W1995570901 @default.
- W1670111524 cites W1997040091 @default.
- W1670111524 cites W1997636725 @default.
- W1670111524 cites W1998472799 @default.
- W1670111524 cites W2000261525 @default.
- W1670111524 cites W2001057180 @default.
- W1670111524 cites W2001987456 @default.
- W1670111524 cites W2004403589 @default.
- W1670111524 cites W2006467548 @default.
- W1670111524 cites W2008406269 @default.
- W1670111524 cites W2009018464 @default.
- W1670111524 cites W2009753108 @default.
- W1670111524 cites W2009891781 @default.
- W1670111524 cites W2010556503 @default.
- W1670111524 cites W2011212993 @default.
- W1670111524 cites W2012760309 @default.
- W1670111524 cites W2016487684 @default.
- W1670111524 cites W2018307939 @default.
- W1670111524 cites W2024256443 @default.
- W1670111524 cites W2024758251 @default.
- W1670111524 cites W2025532545 @default.
- W1670111524 cites W2026293310 @default.
- W1670111524 cites W2029971522 @default.
- W1670111524 cites W2039659389 @default.
- W1670111524 cites W2040125392 @default.
- W1670111524 cites W2040766680 @default.
- W1670111524 cites W2041670884 @default.
- W1670111524 cites W2043941373 @default.
- W1670111524 cites W2044114580 @default.
- W1670111524 cites W2045128315 @default.
- W1670111524 cites W2046636187 @default.
- W1670111524 cites W2047360657 @default.
- W1670111524 cites W2047730662 @default.
- W1670111524 cites W2048668525 @default.
- W1670111524 cites W2050032266 @default.
- W1670111524 cites W2050831054 @default.
- W1670111524 cites W2055201639 @default.
- W1670111524 cites W2055337611 @default.
- W1670111524 cites W2055622548 @default.
- W1670111524 cites W2055835189 @default.
- W1670111524 cites W2061551271 @default.
- W1670111524 cites W2063414487 @default.
- W1670111524 cites W2063719661 @default.
- W1670111524 cites W2065832309 @default.
- W1670111524 cites W2068833172 @default.
- W1670111524 cites W2069310901 @default.
- W1670111524 cites W2070309914 @default.
- W1670111524 cites W2073972117 @default.
- W1670111524 cites W2074461617 @default.
- W1670111524 cites W2077301910 @default.
- W1670111524 cites W2077851905 @default.
- W1670111524 cites W2082872303 @default.
- W1670111524 cites W2085002271 @default.
- W1670111524 cites W2087779989 @default.
- W1670111524 cites W2095233087 @default.
- W1670111524 cites W2095578500 @default.
- W1670111524 cites W2108411017 @default.
- W1670111524 cites W2111199187 @default.
- W1670111524 cites W2112186390 @default.
- W1670111524 cites W2117070592 @default.
- W1670111524 cites W2118025833 @default.
- W1670111524 cites W2119092691 @default.
- W1670111524 cites W2121444033 @default.
- W1670111524 cites W2123323353 @default.
- W1670111524 cites W2138732112 @default.
- W1670111524 cites W2139574761 @default.
- W1670111524 cites W2139609110 @default.
- W1670111524 cites W2140156284 @default.
- W1670111524 cites W2152377514 @default.
- W1670111524 cites W2152627658 @default.
- W1670111524 cites W2154650546 @default.
- W1670111524 cites W2158544130 @default.