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- W1671018652 abstract "Si 29 magic-angle-spinning nuclear-magnetic resonance has been measured on spinel-type cubic silicon nitride (c-Si3N4). c-Si3N4 shows two Si29 resonances at −50.0±0.2 and −225.0±0.2 ppm, corresponding to the tetrahedron SN4 and the octahedron SiN6, respectively. Integration of the spectrum gives SN4/SiN6 about one half that of the spinel structure. Ab initio self-consistent field Hartree–Fock molecular orbital calculations also indicate that the chemical shift for octahedral Si is more negative in nitride than in oxides." @default.
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- W1671018652 date "2001-05-14" @default.
- W1671018652 modified "2023-10-02" @default.
- W1671018652 title "29Si magic-angle-spinning nuclear-magnetic-resonance study of spinel-type Si3N4" @default.
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- W1671018652 doi "https://doi.org/10.1063/1.1372199" @default.
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