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• W1672647257 abstract "Using a combination of atomic-resolution Z-contrast imaging and electron energy-loss spectroscopy (EELS) in the scanning transmission electron microscope, we examine the atomic and electronic structures at the interface between Si3N4 (101¯0) and CeO2−d intergranular film (IGF). Ce atoms are observed to segregate to the interface in a two-layer periodic arrangement, which is significantly different from the structure observed in a previous study. Our EELS experiments show (i) oxygen in direct contact with the terminating Si3N4 open-ring structures, (ii) a change in the Ce valence from a nominal oxidation state of +3 to almost +4 moving from the interface into the IGF, and (iii) a uniform concentration of Si in the film." @default.
• W1672647257 created "2016-06-24" @default.
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• W1672647257 date "2008-08-04" @default.
• W1672647257 modified "2023-10-14" @default.
• W1672647257 title "Atomic resolution study of the interfacial bonding at Si3N4/CeO2−δ grain boundaries" @default.
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• W1672647257 doi "https://doi.org/10.1063/1.2968683" @default.
• W1672647257 hasPublicationYear "2008" @default.
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