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- W1673669249 abstract "The electronic structures of URh (3), UPd (3), UPt (3), and UAu (3) are calculated with the self-interaction corrected local-spin-density approximation. We find that only in URh (3) the f electrons are fully delocalized. UPt (3) has one f electron localized at each U site, while a localized f(2) configuration of the U ion is found for UPd (3). It is predicted that, upon application of a pressure of 25 GPa, UPd (3) will acquire the f(1) configuration and possibly exhibit heavy-fermion behavior. We find that UAu (3) is characterized by the same mixed localized-delocalized f-electron manifold as UPd (3)." @default.
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- W1673669249 date "2002-05-14" @default.
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- W1673669249 title "<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mn>5</mml:mn><mml:mi mathvariant=italic>f</mml:mi></mml:math>Electron Localization-Delocalization Transition from<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi>UPd</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>to<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><…" @default.
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- W1673669249 doi "https://doi.org/10.1103/physrevlett.88.216403" @default.
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