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- W1673801590 abstract "Abstract A high resolution microwave assignment of S -isopropyl fluorothioformate yielded the following rotational constants: A 0 = 4196(1) MHz, B 0 = 1374.23(3) MHz and C 0 = 1159.80(4 MHz, compatible with a syn-gauche (τ 1 (OCSC) = 0°, τ 2 (CSCH) ∼ 40°) conformer. Low resolution microwave spectra of S -isopropyl trifluorothioacetate, cyanothioformate and chlorothioformate each display strong a -type band series compatible with either syn-syn (τ 1 (OCSC) = 0°, τ 2 (CSCH) = 0°) or syn-gauche (τ 1 (OCSC) = 0°, τ 2 (CSCH) ∼ 60°) conformers. Experimental B+C values are 1211.7(6), 1839.6(7) and 1814.6(5), (1774.4(5), 37 Cl) MHz for the trifluorothioacetate, cyanothioformate and chlorothioformate, respectively. S -isopropyl trifluorothioacetate also displays a weak band series with a B+C value of 1310.2(5) MHz compatible with a syn-anti (τ 1 (OCSC) = 0°, τ 2 (CSCH) = 180°) structure. Torsionally excited species freely rotating about τ 2 have been previously observed in S -ethyl thioesters but are not observed in S -isopropyl thioesters indicating a higher torsional barrier for the S -isopropyl compounds." @default.
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- W1673801590 date "1979-01-01" @default.
- W1673801590 modified "2023-09-27" @default.
- W1673801590 title "Low resolution microwave spectroscopy" @default.
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- W1673801590 doi "https://doi.org/10.1016/0022-2860(79)80290-2" @default.
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