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- W1674667067 abstract "The structure of the title compound, [Co(NO2)2(NH2CH2CH2NH2)2][Co(NO2)4(NH2CH2CH2NH2)]·H2O, was redetermined with a modern CCD-equipped diffractometer. In comparison with the original determination based on photographic data [Kushi et al. (1976 ▶). Inorg. Nucl. Chem. Lett. 12, 629-633], the current study allows the location of reliable postions for the H atoms and thus leads to better understanding of the inter-ionic and inter-molecular inter-actions. The crystal structure consists of an octa-hedrally coordinated cationic Co(III) complex ion, an octa-hedrally coordinated anionic Co(III) complex ion and a lattice water mol-ecule. The complex cation, complex anion and lattice water mol-ecule are connected by an intricate network of O-H⋯O and N-H⋯O hydrogen bonds, forming a three-dimensional structure." @default.
- W1674667067 created "2016-06-24" @default.
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- W1674667067 date "2012-12-15" @default.
- W1674667067 modified "2023-10-17" @default.
- W1674667067 title "Redetermination of<i>cis</i>-bis(ethylenediamine-κ<sup>2</sup><i>N</i>,<i>N</i>′)bis(nitrito-κ<i>N</i>)cobalt(III) (ethylenediamine-κ<sup>2</sup><i>N</i>,<i>N</i>′)tetrakis(nitrito-κ<i>N</i>)cobaltate(III) monohydrate" @default.
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- W1674667067 doi "https://doi.org/10.1107/s1600536812050325" @default.
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