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- W1678158391 abstract "Abstract Theoretical calculations on tris(4-trifluoromethyltetrafluorophenyl)phosphine, 1 , and spectroscopic studies of its complexes, trans -[PtCl 2 {P(C 6 F 4 CF 3 -4) 3 } 2 ], 3 , and trans -[RhCl(CO){P(C 6 F 4 CF 3 -4) 3 } 2 ], 4 , indicate that it is a poorer σ donor than tris(pentafluorophenyl)phosphine. The structures of 1 , 3 and 4 have been determined by single crystal X-ray diffraction, and indicate that the cone angle of 1 is the same as that of tris(pentafluorophenyl)phosphine." @default.
- W1678158391 created "2016-06-24" @default.
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- W1678158391 date "2015-12-01" @default.
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- W1678158391 title "Structural and electronic properties of tris(4-trifluoromethyltetrafluorophenyl)phosphine" @default.
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- W1678158391 doi "https://doi.org/10.1016/j.jfluchem.2015.08.014" @default.
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