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- W167908102 abstract "Mossbauer spectroscopy is a valuable technique used in the structural and magnetic analysis of the microscopic cores of ferritin. Magnetic fluctuation effects occur in small particles, and it is the great sensitivity of Mossbauer spectroscopy to these fluctuations that gives the technique its power as an investigative tool. Combining Mossbauer spectroscopy with complementary techniques such as HRTEM and electron diffraction enables the core properties to be extensively characterized. Magnetically ordered materials of small dimensions are likely to be anisotropic, producing easy directions of magnetization separated by anisotropy energy barriers. Under most conditions, the magnetization of the particle will be positioned along easy direction. But, if the energy of the spin system is sufficient to overcome the anisotropy energy barrier, the magnetization may fluctuate between the easy directions of the material. This effect—known as superparamagnetic relaxation—is important in small particles as the energy barrier is dependent on particle size. Therefore, the thermal energy of the spin system is comparable to the energy barrier even at low temperatures. The Mossbauer spectra of the reconstituted cores indicate that the phosphate-free growth conditions produce cores with good magnetic ordering and of high anisotropy." @default.
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- W167908102 date "1992-01-01" @default.
- W167908102 modified "2023-09-26" @default.
- W167908102 title "A Mössbauer Study of the Superparamagnetic Properties of Reconstituted E. Coli BFR" @default.
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- W167908102 doi "https://doi.org/10.1016/b978-0-444-89552-3.50050-5" @default.
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