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- W168020384 abstract "The HTFFR (high–temperature fast-flow reactor) and Metals–HTP (high–temperature photochemistry) techniques for measurements of the kinetics of metallic species in the 300 to 1900 K temperature range are described. Their relative advantages and disadvantages are discussed. The most extensive data set obtained by the HTFFR technique concerns the oxidation reactions of Al, AlO and AlCl. The various temperature dependences observed for these are summarized and discussed. The pre–exponentials of the rate coefficients of several of these reactions are compared to each other and to those obtained from HTFFR measurements on BCl oxidation reactions. HTP results for the Na/O2/N2 and Cr/O2/Ar systems, as well as the Cu + N2O reaction, are given. It is shown that for various groups of metal atom + N2O reactions and for reactions of AlCl, BCl, BF and BH with various oxygen oxidants, the activation barriers correlate well with the ionization potentials plus the s–p (or σ–π) promotion energies of the metal species minus the electron affinities of the oxidants. These correlations can be explained on the basis of resonance theory and together constitute a generalization of more limited correlations for activation energies, already in common use. Semi–empirical calculations of the barrier energies based on the present approach are shown to agree well with experiment." @default.
- W168020384 created "2016-06-24" @default.
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- W168020384 date "1992-01-01" @default.
- W168020384 modified "2023-09-27" @default.
- W168020384 title "Homogeneous Kinetics of Metal Species over Wide Temperature Ranges: Techniques, Measurements, and Correlations" @default.
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- W168020384 doi "https://doi.org/10.1016/b978-0-444-89070-2.50009-8" @default.
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