Matches in SemOpenAlex for { <https://semopenalex.org/work/W168047546> ?p ?o ?g. }
- W168047546 endingPage "430" @default.
- W168047546 startingPage "424" @default.
- W168047546 abstract "The redox centers in the tungsten-containing formate dehydrogenase from Clostridium thermoaceticum were examined by potentiometric titration and electron paramagnetic resonance spectroscopy. At low temperature two overlapping iron-sulfur signals which correlated with enzymatic activity were observed with formal potentials near -400 mV vs. SHE. Based on their temperature dependences, one signal is assigned to a reduced Fe2S2 cluster and one to a reduced Fe4S4 cluster. Quantitation of signal intensity suggests two Fe2S2 and two Fe4S4 clusters per formate dehydrogenase molecule. Another signal (g = 2.101, 1.980, 1.950) present in low concentrations at more negative potentials was observable up to 200 degrees K and is not attributed to any iron-sulfur cluster. The possible origin of this signal is analyzed using ligand field theory, and the redox behavior is considered with respect to possible ligation at the active site." @default.
- W168047546 created "2016-06-24" @default.
- W168047546 creator A5004772621 @default.
- W168047546 creator A5016800633 @default.
- W168047546 creator A5024342453 @default.
- W168047546 creator A5025794405 @default.
- W168047546 creator A5052784662 @default.
- W168047546 date "1987-12-01" @default.
- W168047546 modified "2023-09-25" @default.
- W168047546 title "Electron paramagnetic resonance studies of the tungsten-containing formate dehydrogenase from Clostridiumthermoaceticum" @default.
- W168047546 cites W1504832378 @default.
- W168047546 cites W1508578483 @default.
- W168047546 cites W1536295539 @default.
- W168047546 cites W1556964559 @default.
- W168047546 cites W1566131755 @default.
- W168047546 cites W1966031088 @default.
- W168047546 cites W1973202990 @default.
- W168047546 cites W1979011973 @default.
- W168047546 cites W1986559494 @default.
- W168047546 cites W1992774676 @default.
- W168047546 cites W1994074432 @default.
- W168047546 cites W2037646029 @default.
- W168047546 cites W2051186177 @default.
- W168047546 cites W2064785423 @default.
- W168047546 cites W2072173342 @default.
- W168047546 cites W2119458676 @default.
- W168047546 cites W2334621961 @default.
- W168047546 cites W2337320700 @default.
- W168047546 cites W43135304 @default.
- W168047546 doi "https://doi.org/10.1016/0006-291x(87)90384-6" @default.
- W168047546 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/2827642" @default.
- W168047546 hasPublicationYear "1987" @default.
- W168047546 type Work @default.
- W168047546 sameAs 168047546 @default.
- W168047546 citedByCount "37" @default.
- W168047546 countsByYear W1680475462014 @default.
- W168047546 countsByYear W1680475462017 @default.
- W168047546 countsByYear W1680475462021 @default.
- W168047546 countsByYear W1680475462022 @default.
- W168047546 countsByYear W1680475462023 @default.
- W168047546 crossrefType "journal-article" @default.
- W168047546 hasAuthorship W168047546A5004772621 @default.
- W168047546 hasAuthorship W168047546A5016800633 @default.
- W168047546 hasAuthorship W168047546A5024342453 @default.
- W168047546 hasAuthorship W168047546A5025794405 @default.
- W168047546 hasAuthorship W168047546A5052784662 @default.
- W168047546 hasConcept C113196181 @default.
- W168047546 hasConcept C116569031 @default.
- W168047546 hasConcept C121332964 @default.
- W168047546 hasConcept C124614425 @default.
- W168047546 hasConcept C139210041 @default.
- W168047546 hasConcept C147789679 @default.
- W168047546 hasConcept C161790260 @default.
- W168047546 hasConcept C164866538 @default.
- W168047546 hasConcept C170493617 @default.
- W168047546 hasConcept C17525397 @default.
- W168047546 hasConcept C178790620 @default.
- W168047546 hasConcept C179104552 @default.
- W168047546 hasConcept C181199279 @default.
- W168047546 hasConcept C184779094 @default.
- W168047546 hasConcept C184866935 @default.
- W168047546 hasConcept C185592680 @default.
- W168047546 hasConcept C187961010 @default.
- W168047546 hasConcept C199360897 @default.
- W168047546 hasConcept C2776317432 @default.
- W168047546 hasConcept C2778428456 @default.
- W168047546 hasConcept C2780178953 @default.
- W168047546 hasConcept C41008148 @default.
- W168047546 hasConcept C43617362 @default.
- W168047546 hasConcept C46141821 @default.
- W168047546 hasConcept C518881349 @default.
- W168047546 hasConcept C55493867 @default.
- W168047546 hasConcept C55904794 @default.
- W168047546 hasConcept C8010536 @default.
- W168047546 hasConceptScore W168047546C113196181 @default.
- W168047546 hasConceptScore W168047546C116569031 @default.
- W168047546 hasConceptScore W168047546C121332964 @default.
- W168047546 hasConceptScore W168047546C124614425 @default.
- W168047546 hasConceptScore W168047546C139210041 @default.
- W168047546 hasConceptScore W168047546C147789679 @default.
- W168047546 hasConceptScore W168047546C161790260 @default.
- W168047546 hasConceptScore W168047546C164866538 @default.
- W168047546 hasConceptScore W168047546C170493617 @default.
- W168047546 hasConceptScore W168047546C17525397 @default.
- W168047546 hasConceptScore W168047546C178790620 @default.
- W168047546 hasConceptScore W168047546C179104552 @default.
- W168047546 hasConceptScore W168047546C181199279 @default.
- W168047546 hasConceptScore W168047546C184779094 @default.
- W168047546 hasConceptScore W168047546C184866935 @default.
- W168047546 hasConceptScore W168047546C185592680 @default.
- W168047546 hasConceptScore W168047546C187961010 @default.
- W168047546 hasConceptScore W168047546C199360897 @default.
- W168047546 hasConceptScore W168047546C2776317432 @default.
- W168047546 hasConceptScore W168047546C2778428456 @default.
- W168047546 hasConceptScore W168047546C2780178953 @default.
- W168047546 hasConceptScore W168047546C41008148 @default.
- W168047546 hasConceptScore W168047546C43617362 @default.
- W168047546 hasConceptScore W168047546C46141821 @default.