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- W1690089029 abstract "Temperature depenences of the pitch of cholesteric helix in solutions of poly(y-benzyl-L-glutamate) in N,N-dimethylformamide and N-methyl-2-pyrrolidone were measured for various molar masses of poly(γ-benzyl-L-glutamate). It was found that in N-methyl-2-pyrrolidone inversion of the cholesteric helix takes place, i. e., that the right-handed helix changes to the lefthanded one. By using an equation derived by Kimura, the temperatures at which the system has a nematic order were determined. The results obtained allow the statement that an important role in the inversion of the cholesteric helix in poly(γ-benzyl-L-glutamate) solutions is played by conformational changes in side chains of the polypeptide molecule." @default.
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- W1690089029 date "1988-01-01" @default.
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- W1690089029 doi "https://doi.org/10.1002/macp.1988.021890119" @default.
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