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• W1697071020 endingPage "291" @default.
• W1697071020 startingPage "239" @default.
• W1697071020 abstract "Publisher Summary This chapter deals with the selectivity of an electrophilic carbon centre carrying a nucleofuge (RX) or of a solvolytically generated carbocation species (R + ) toward the two nucleophilic solvent components. The chapter explains the solvent-induced changes in the selectivity values k A /k B in A–B mixtures (A and B being water (W), methanol (M), ethanol (E) or trifluoroethanol (TFE)). The chapter explains the selectivity of a single electrophilic species usually varies when the solvent composition is changed, owing to different responses of the individual rate constants k A and k B to the composition change. Solvent sorting around the electrophile does not explain the trends found for the variations of the individual rate constants. A proper analysis of changes in k A /k B must be in terms of the changes in the individual rate constants. Because the selectivities are derived parameters, the importance of their solvent-induced changes as mechanistic probes will decrease if the values of the individual rate constants at various solvent compositions are known." @default.
• W1697071020 created "2016-06-24" @default.
• W1697071020 creator A5005482387 @default.
• W1697071020 creator A5042952503 @default.
• W1697071020 date "1992-01-01" @default.
• W1697071020 modified "2023-10-17" @default.
• W1697071020 title "Solvent-induced Changes in the Selectivity of Solvolyses in Aqueous Alcohols and Related Mixtures" @default.
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