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- W1697521256 abstract "1,3-Dipolar cycloadditions of nitrones with pentafluorosulfanyl-substituted acrylic ester and amides afforded new trisubstituted pentafluorosulfanylated isoxazolidines in moderate yields as 4-SF5-regioisomers. Theoretical calculations were carried out and the regioselectivity could be explained by the fact that the 5-SF5-regioisomer probably undertook a spontaneous degradation in the reaction medium via the loss of pentafluorosulfanyl anion. Diastereoselectivity of the 1,3-dipolar cycloadditions was also assessed according to NMR and X-ray diffraction analysis." @default.
- W1697521256 created "2016-06-24" @default.
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- W1697521256 date "2015-10-01" @default.
- W1697521256 modified "2023-10-18" @default.
- W1697521256 title "Synthesis of SF5-substituted isoxazolidines using 1,3-dipolar cycloaddition reactions of nitrones with pentafluorosulfanyl acrylic esters and amides" @default.
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- W1697521256 doi "https://doi.org/10.1016/j.tet.2015.08.050" @default.
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