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- W1697548873 abstract "To address the question of the role of chirality at the metal in enantioselective catalysis, a pseudo-tetrahedral three-legged piano-stool complex has been prepared, i.e. [RuCl(C26H27N2P)](CF3SO3). Anchoring a phosphine and a pyrazole tether to an arene (PArN) yields, after η6:η1:η1 coordination to ruthenium, [{η6:η1:η1-(PArN)}RuCl]+ as a 1:1 mixture of enantiomers. Unfortunately, all attempts to resolve the enantiomers failed. The structure solution revealed the presence of racemic crystals." @default.
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- W1697548873 date "2000-12-15" @default.
- W1697548873 modified "2023-10-16" @default.
- W1697548873 title "Chloro(1-{3-[2-(diphenylphosphanyl-κP)ethyl]-η6-benzyl}-3,5-dimethyl-1H-pyrazole-κN2)ruthenium(II) trifluoromethanesulfonate" @default.
- W1697548873 cites W2115548957 @default.
- W1697548873 doi "https://doi.org/10.1107/s0108270100015705" @default.
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