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- W1701796558 abstract "The kinetics of the radical polymerisation of acrylamide in aqueous solution with 4,4′-azobis-(4-cyanopentanoic acid) as initiator were investigated. The overall rate of reaction is proportional to the monomer concentration and to the square root of the initiator concentration. Determinations of the degree of polymerisation indicate that chain transfer to monomer probably occurs under the experimental conditions employed. An empirical relation between degree of polymerisation and initiator concentration is given and the mechanism of chain termination is discussed. Es wurde am Acrylamid die Kinetik der durch γ-Azo-bis-γ-cyan-n-valeriansäure initiierten radikalischen Polymerisation in wäßriger Lösung untersucht. Die Bruttoreaktionsgeschwindigkeit ist proportional der Monomerenkonzentration und proportional der Wurzel aus der Initiator-Konzentration. Aus der Bestimmung des Polymerisationsgrades ergibt sich, daß unter den angewandten Versuchsbedingungen wahrscheinlich Kettenübertragung durch das Monomere stattfindet. Eine empirische Beziehung zwischen Polymerisationsgrad und Initiatorkonzentration wird mitgeteilt. Schließlich wird der Mechanismus des Kettenabbruches diskutiert." @default.
- W1701796558 created "2016-06-24" @default.
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- W1701796558 date "1962-01-01" @default.
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- W1701796558 doi "https://doi.org/10.1002/macp.1962.020540105" @default.
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