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- W170275732 abstract "This chapter presents the electron paramagnetic resonance (EPR) evidence for the involvement of a discrete manganese (Mn) cluster in O2 evolution. The requirement for Mn in the four electron oxidation of two water molecules to form molecular oxygen by photosynthesis is well established. A minimal quantity of 4 Mn ions per PS-II unit appears to be required for full O2 evolution capacity, based upon Mn extraction and the enrichment of Mn in PS-II preparations. It is widely accepted that this Mn is associated with protein that is bound to the inner surface of the thylakoid membrane. Illumination of dark-adapted chloroplasts by a train of short flashes results in the periodic release of O2 after each fourth flash. A newly discovered EPR signal in membranes of spinach, a green alga, and a blue-green alga, is observable below 8 K and exhibits hyperfine structure characteristic of an even-spin cluster of two or four Mn ions." @default.
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- W170275732 date "1983-01-01" @default.
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- W170275732 title "EPR EVIDENCE FOR THE INVOLVEMENT OF A DISCRETE MANGANESE CLUSTER IN O2 EVOLUTION1,1Supported by a Searle Scholars Award and grants by the USDA CRGO and the SERI division of the DOE, grant no. DE-FG02–80CS84003 A003.22This article is dedicated to the memory of Professor Allen Scattergood." @default.
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- W170275732 doi "https://doi.org/10.1016/b978-0-12-372360-4.50022-5" @default.
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