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• W1705975914 abstract "We report observation of long-lived spin-singlet states in a 13C-1H spin pair at zero magnetic field. In 13C-labeled formic acid, we observe spin-singlet lifetimes as long as 37 seconds, about a factor of three longer than the T1 lifetime of dipole polarization in the triplet state. We also observe that the lifetime of the singlet-triplet coherence, T2, is longer than T1. Moreover, we demonstrate that this singlet states formed by spins of a heteronucleus and a 1H nucleus, can exhibit longer lifetimes than the respective triplet states in systems consisting of more than two nuclear spins. Although long-lived homonuclear spin-singlet states have been extensively studied, this is the first experimental observation of analogous spin-singlets consisting of a heteronucleus and a proton." @default.
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• W1705975914 date "2013-10-04" @default.
• W1705975914 modified "2023-09-27" @default.
• W1705975914 title "Long-lived heteronuclear spin-singlet states" @default.
• W1705975914 hasPublicationYear "2013" @default.
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