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- W170881460 abstract "The (liquid + liquid) phase equilibria of the binary closed-loop system {xc-(CH2)4O + (1 −x)H2O} and additionally the effect of small amounts of dissolved (NH4)2SO4were investigated in the temperature range from 315.8 K to 405 K and at pressures up to 135 MPa. The measurements were performed in an optical high-pressure cell with magnetic stirring according to the synthetic method. Phase separation was detected by visual observation. The experimentalp(T)isopleths are presented and discussed. They show that the closed miscibility gap of the salt-free system disappears at (24.7 ± 0.4) MPa where the loop degenerates to a point at (376.9 ± 0.2) K andx≈ 0.22. Thus the system corresponds to type-VI phase behaviour according to the classification of van Konynenburg and Scott. Added ammonium sulfate is shown to have a strong out-salting effect." @default.
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- W170881460 date "1995-04-01" @default.
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- W170881460 title "(Liquid + liquid) phase equilibria at high pressures" @default.
- W170881460 doi "https://doi.org/10.1006/jcht.1995.0036" @default.
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