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- W170908535 abstract "Isothermal measurements of the crystallization kinetics of icosahedral ${mathrm{Al}}_{86}$${mathrm{Mn}}_{14}$ were made by differential scanning calorimetry and electrical resistivity in the temperature range 593--723 K. Transmission electron microscopy investigations of as-quenched samples showed that the icosahedral phase (i phase) occurs as dendritic nodules separated by ensuremath{alpha}-Al. On crystallization, ${mathrm{Al}}_{6}$Mn nucleates at the i-phase boundary and grows into the i phase, while consuming the ensuremath{alpha}-Al. An effective-medium theory is used to relate resistance changes to the volume fraction transformed. A Johnson-Mehl-Avrami analysis for the kinetics of transformation indicates continuous nucleation with diffusion-limited growth. Nonisothermal differential scanning calorimetry measurements were made and analyzed using a numerical model that assumes simultaneous nucleation and growth. Crude estimates are given for the diffusion coefficient for growth of the crystal phase in the i phase and a lower bound for the i-phase ${mathrm{Al}}_{6}$Mn interfacial energy." @default.
- W170908535 created "2016-06-24" @default.
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- W170908535 date "1988-03-15" @default.
- W170908535 modified "2023-09-26" @default.
- W170908535 title "Crystallization of icosahedralAl86Mn14" @default.
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- W170908535 doi "https://doi.org/10.1103/physrevb.37.3940" @default.
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