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- W171623757 abstract "The knowledge of the micropore-size distribution function is important for describing many physicochemical processes occurring in the micropores of a solid. This distribution function can be evaluated by inverting the integral equation for gas adsorption on microporous solids. There are, at least, two problems associated with solution of this integral equation: (i) its numerical ill-posedness and (ii) the unknown local adsorption isotherm. To deal with the first problem, we suggest the use of the regularization method, which is suitable for solving the ill-posed problems. As regards the second problem the semi-empirical Dubinin-Astakhov equation is most often used to represent adsorption in the uniform micropores. In this work Monte Carlo simulations are carried out in order to propose a more realistic local adsorption model. These simulations suggest the use of the two-term Fowler-Guggenheim equation for describing local adsorption." @default.
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- W171623757 date "1993-01-01" @default.
- W171623757 modified "2023-09-26" @default.
- W171623757 title "Evaluation of the Micropore-Size Distribution Function from Gas Adsorption Data by Using a Simple Molecular Model" @default.
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- W171623757 doi "https://doi.org/10.1016/s0167-2991(08)63499-0" @default.
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