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- W171852007 abstract "The effect of pH on chlorate formation during chlorine dioxide delignification of oxygen delignified kraft pulp was studied. Chlorate formation was found to increase slightly when pH was increased from 1.8 to 2.5; further increase of pH decreased chlorate formation. The above phenomenon is explained by the combination of two mechanisms, one by the reaction between hypochlorous acid (HClO) and chlorite, another by the effect of chlorine on the regeneration of chlorine dioxide. The first mechanism suggests that chlorate formation would be highly dependent on HClO concentration, which decreases with increasing pH and causes chlorate formation to trend similarly. The second mechanism suggests that chlorine favours the regeneration of chlorine dioxide while HClO favours chlorate formation, thus lowering the pH from about 4 to the acidic extreme should decrease chlorate formation. The two opposite effects lead to the maximum formation of chlorate at around pH 2.5." @default.
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- W171852007 date "2004-11-01" @default.
- W171852007 modified "2023-09-23" @default.
- W171852007 title "Mechanism of Chlorate Formation in Chlorine Dioxide Delignification" @default.
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