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- W1719967288 abstract "Atoms have only translational and electronic energy, but molecules have rotational and vibrational energy in addition to translational and electronic energy. The Born-Oppenheimer approximation is used to separate the electronic motion from the rotational and vibrational motion of molecules. To a good approximation, translational, rotational, and vibrational motions make separate contributions to the molecular energy of a diatomic molecule. To a first approximation, the vibrational energy of a diatomic molecule is that of a harmonic oscillator, and the rotation is that of a rigid rotor. The equilibrium populations of rotational, vibrational, and electronic states of molecules are described by the Boltzmann probability distribution. The rotational and vibrational energies of polyatomic molecules can be discussed in the Born-Oppenheimer approximation." @default.
- W1719967288 created "2016-06-24" @default.
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- W1719967288 date "2000-01-01" @default.
- W1719967288 modified "2023-09-26" @default.
- W1719967288 title "Translational, Rotational, and Vibrational States of Atoms and Molecules" @default.
- W1719967288 doi "https://doi.org/10.1016/b978-012508345-4/50022-8" @default.
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