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• W172353037 abstract "Pervasive but commonly unappreciated hydrogen impurities in the indicated divalent metals or in reaction systems at high temperature have led to misreports of Ca5Pn3H, Sr5Pn3H, Eu5Pn3H and Yb5Pn3H for Pn=Sb, Bi as binary phases with the orthorhombic β-Yb5Sb3-type structure (space group Pnma). Sm5Bi3H is a new member and contains Sm2+. These phases do not form, or are decomposed into hexagonal Mn5Si3(Hx)-type analogues, in heated systems under dynamic high vacuum. The structure of these hydrides is better described as orthorhombic Ca5Sb3F-type with H or F in tetrahedral interstitial sites; Sr5Pn3F and Y5Sb3F are new examples of the latter group. Both the Ca5Sb3F- and Mn5Si3-type A5Pn3Hx phases show appreciable ranges of hydrogen content. The relative stabilities of the orthorhombic hydrides increase with decreasing cation size and, secondarily, for Bi over Sb. EHMO band calculations for the reported binary Ca5Bi3 (Yb5Sb3-type) structure signal the presence of a bound interstitial by the appearance of underutilized calcium states in a half-filled band at EF that are displaced on hydrogen inclusion in the correct site. Magnetic and resistivity data are also reported." @default.
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• W172353037 date "1998-01-01" @default.
• W172353037 modified "2023-10-18" @default.
• W172353037 title "Hydrogen stabilization." @default.
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• W172353037 doi "https://doi.org/10.1016/s0925-8388(97)00320-4" @default.
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