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• W1729011330 startingPage "2864" @default.
• W1729011330 abstract "Abstract Two new compounds with Co‐centered Sn 9 clusters were obtained by the extraction directly from the intermetallic precursor K 4.79 Co 0.79 Sn 9 in ethylenediamine with addition of cryptand [2.2.2]. The anions [Co 0.68 @Sn 9 ] 4– in K[K([2.2.2]crypt)] 3 [Co 0.68 @Sn 9 ] ( 1 ) consisting of overlaying [Co@Sn 9 ] 4– and [Sn 9 ] 4– cluster anions are connected by K atoms to form infinite $rm^{1}_{infty}$ K[Co 0.68 @Sn 9 ] chains. The anions [Co 2 @Sn 17 ] 5– in [K([2.2.2]crypt)] 5 [Co 2 @Sn 17 ] · en · tol ( 2 ) are built from two [Co@Sn 9 ] sharing one common Sn atom, with the same composition but a different conformation as in the previously reported [K([2.2.2]crypt)] 5 [Co 2 @Sn 17 ]. Quantum chemical calculations for the different conformers of [Co 2 @Sn 17 ] 5– reveal that both conformers are rather close in energy and that the short intercluster Sn–Sn distance in 2 does not originate from attractive interactions." @default.
• W1729011330 created "2016-06-24" @default.
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• W1729011330 date "2014-10-06" @default.
• W1729011330 modified "2023-10-12" @default.
• W1729011330 title "Metal-Centered Zintl Ions Isolated by Direct Extraction from Endohedral Intermetallic Precursor: [Co_1-<i>x</i>@Sn₉]^4-(<i>x</i>≈ 0.32) and [Co₂@Sn₁₇]^5-" @default.
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• W1729011330 doi "https://doi.org/10.1002/zaac.201400379" @default.
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