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- W1729236827 endingPage "249" @default.
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- W1729236827 abstract "This chapter provides an overview of the inclusion complexes of cyclomalto-oligosaccharides (cyclodextrins). Inclusion complexes are chemical species consisting of two or more associated molecules in which one of the molecules—the “host”—forms or possesses a cavity into which it can admit a “guest” molecule, resulting in a stable association without formation of any covalent bonds. Secondary forces are alone responsible for the maintenance of the integrity of all inclusion complexes. One of the most important properties of the cyclodextrins is their ability to form complexes with a variety of organic and inorganic compounds. 1H-Nuclear magnetic resonance (NMR) spectroscopy provided the first direct evidence of inclusion within the cyclodextrin cavity in solution. Using aromatic “guest” molecules, it was found that, on the addition of the guest, the resonances of the hydrogen atoms of the cyclodextrin situated on the inside of the cavity were shifted significantly upfield due to shielding by the aromatic guest. This chapter discusses determination of the structure of the cyclodextrins, and formation of the cyclodextrins from starch. It provides details about formation of inclusion complexes, detection of complex formation, and thermodynamics of complex formation. Kinetics of complex formation is also explained in the chapter." @default.
- W1729236827 created "2016-06-24" @default.
- W1729236827 creator A5038060167 @default.
- W1729236827 creator A5052949556 @default.
- W1729236827 creator A5056320301 @default.
- W1729236827 date "1988-01-01" @default.
- W1729236827 modified "2023-09-27" @default.
- W1729236827 title "Inclusion Complexes of the Cyclomalto-Oligosaccharides (Cyclodextrins)" @default.
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