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- W1733387544 abstract "Die Reaktion des Dithiophosphorsäurefluoridpyrididiumbetains Py · PS2F (Py = Pyridin) (1) mit flüssigem Ammoniak führt zum Ammonium-amidofluorodithiophosphat, NH4[PS2F(NH2)] (2), das als reine kristalline Verbindung isoliert wurde. Bei der Ammonolyse von 2 wird quantitativ Ammonium-diamidodithiophosphat, NH4[PS2F(NH2)] (3) gebildet. Durch nucleophilen Angriff von 2 am Py · PS2F entsteht Imido-bis(fluorodithiophosphat) (4), [FPS2NHPS2F]2−. Die Hydrolyse und Methanolyse von 2 wurden 31P-NMR-spektroskopisch untersucht. Preparation and Properties of Ammonium Amidofluoro Dithiophosphate Reaction of the dithiophosphoric acid fluoride betaine Py · PS2F, (Py = pyridine) 1, with liquid ammonia yields ammonium amido-fluoro dithiophosphate, NH4[PS2F(NH2)] (2), which has been prepared as a pure, crystalline compound. On ammonolysis of 2 diamido dithiophosphate, NH4[PS2F(NH2)] (3), is obtained in quantitative yield. By nucleophilic attack of 2 on Py · PS2F, the imido-bis-(fluorodithiophosphate) [FPS2NHPS2F]2− (4) is formed. Hydrolysis and methanolysis of 2 has been studied by 31P NMR spectroscopy." @default.
- W1733387544 created "2016-06-24" @default.
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- W1733387544 date "1989-09-01" @default.
- W1733387544 modified "2023-09-26" @default.
- W1733387544 title "�ber Darstellung und Eigenschaften von Ammonium-amido-fluoro-dithiophosphat" @default.
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- W1733387544 doi "https://doi.org/10.1002/zaac.19895760103" @default.
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