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- W1736522047 abstract "Kinetics of the reaction of acetylene with two phenylmagnesium bromide reagents of different magnesium bromide content (Br/Mg 1.08 and 1.27) in diethyl ether in the presence of various additions of triethylamine (TEA) were investigated. The reagent of average stoichiometry PhMgBr·2TEA reacts about 20 000 times faster than in the absence of the amine. Elevated content of magnesium bromide in the reagent enhances the accelerating effect of the amine. The complicated relationships obtained enabled us to draw conclusions on the structure and reactivity of the title complexes. At moderate magnesium bromide content species 2PhMgBr·MgBr2 dominate and preferentially complex with TEA giving solvates more reactive than PhMgBr·TEA, whose formation takes place at a higher amine content." @default.
- W1736522047 created "2016-06-24" @default.
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- W1736522047 date "1999-07-01" @default.
- W1736522047 modified "2023-09-27" @default.
- W1736522047 title "Complexes PhMgBr·nMgBr2·mNEt3 in the reaction with acetylene" @default.
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- W1736522047 doi "https://doi.org/10.1016/s0022-328x(99)00136-9" @default.
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